The culprit has been found.
The mentioned file tape job No.2 has to back up some directories from the old VBR server, nightly backups from 18 VM's I still haven't found the time to move them to the new server and two directories containing backups from Backup Exec.
So these seemed to be static files, but there's one directory named .\REPLICA containing the replica files from these 18 VM's and the replica jobs are starting at 06:00AM. The .\REPLICA directory was among the last entry of the tape job definitions and so the replicas were starting at the runtime of the tape job.
Now I separated the definitions and put the .\REPLICA dir on the first line and voila, no more errors.
Oh and the message was:
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Volume \\ntsrv02\VEEAM_DATA have 34 problems. Details: File not found.
This is not very meaningful.